亞苄基丙二腈
| 亞苄基丙二腈 | |
|---|---|
propanedinitrile.png)
| |
| 英文名 | 2-(Phenylmethylene)propanedinitrile |
| 別名 | 1,1-二氰基-2-苯基乙烯 |
| 識別 | |
| CAS號 | 2700-22-3 
|
| SMILES |
|
| 性質 | |
| 化學式 | C10H6N2 |
| 摩爾質量 | 154.17 g·mol−1 |
| 外觀 | 無色晶體[1] |
| 熔點 | 83 °C（356 K）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
亞苄基丙二腈是一種有機化合物，化學式為C10H6N2。它可由苯甲醛和丙二腈反應得到。[2]它和硝基甲烷反應，得到2-(2-硝基-1-苯乙基)丙二腈。[3]和2-碘-2-甲基丙烷在過氧化苯甲酰和三乙基鋁的存在下反應，得到α-叔丁基苄基丙二腈。[4]
參考文獻
[編輯]- ^ 1.0 1.1 G. Rajesh Krishnan, Krishnapillai Sreekumar. First Example of Organocatalysis by Polystyrene-Supported PAMAM Dendrimers: Highly Efficient and Reusable Catalyst for Knoevenagel Condensations. European Journal of Organic Chemistry. 2008-10, 2008 (28): 4763–4768 [2020-07-04]. doi:10.1002/ejoc.200800516 （英語）.
- ^ Samahe Sadjadi, Maryam Akbari, Fatemeh Ghoreyshi Kahangi, Majid M. Heravi. Acidic polymer containing sulfunic acid and carboxylic acid groups heterogenized with natural clay: A novel metal free and heterogeneous catalyst for acid-catalyzed reactions. Polyhedron. 2020-03, 179: 114375 [2020-07-04]. doi:10.1016/j.poly.2020.114375 （英語）.
- ^ David Michaud, Françoise Texier-Boullet, Jack Hamelin. Michael Monoaddition of Nitromethane on Gem-Diactivated Alkenes in Dry Media Coupled with Microwave Irradiation. Tetrahedron Letters. 1997-10, 38 (43): 7563–7564 [2020-07-04]. doi:10.1016/S0040-4039(97)10035-1. （原始內容存檔於2022-04-26） （英語）.
- ^ Jing-Yuan Liu, Yoeng-Jiunn Jang, Wen-Wei Lin, Ju-Tsung Liu, Ching-Fa Yao. Triethylaluminum- or Triethylborane-Induced Free Radical Reaction of Alkyl Iodides and α,β-Unsaturated Compounds. The Journal of Organic Chemistry. 2003-05, 68 (10): 4030–4038 [2020-07-04]. ISSN 0022-3263. doi:10.1021/jo020681b （英語）.