2-氟-4-氯-6-溴碘苯

2-氟-4-氯-6-溴碘苯
别名	1-溴-5-氯-3-氟-2-碘苯
识别
CAS号	201849-16-3
PubChem	44557939
SMILES	FC=1C=C(Cl)C=C(Br)C1I;
性质
化学式	C6H2BrClFI
摩尔质量	335.34 g·mol−1
密度	2.331±0.06 g/cm3（20 °C）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2-氟-4-氯-6-溴碘苯是一种有机化合物，化学式为C₆H₂BrClFI，它是氟氯溴碘苯的同分异构体之一。它可由2-氟-4-氯-6-溴苯胺、亚硝酸和碘化亚铜反应制得。^[2]在三乙胺存在下，它和苯乙炔在乙酸钯、Cu₄I₄簇配合物催化下反应，可以得到3-氟-5-氯-1-溴-2-苯乙炔基苯；和1,3-二乙炔基苯在催化下反应，得到3-氟-5-氯-1-溴-2-[(3-乙炔基苯基)乙炔基]苯。^[3]

参考文献

^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2023 ACD/Labs). Retrieved from SciFinder. [2023-11-30].
^ 邢其锋; 丰佩川; 孙伟; 胡灵峰; 陈跃. 一种化合物、空穴传输材料、有机电致发光器件和显示装置. 2020. CN111732530A
^ Xiaogang Yang, Dong Lu, Wenjian Guan, Shuang-Feng Yin, Nobuaki Kambe, and Renhua Qiu. Synthesis of (Deoxy)difluoromethylated Phosphines by Reaction of R2P(O)H with TMSCF3 and Their Application in Cu(I) Clusters in Sonogashira Coupling. J. Org. Chem. 2022, 87, 12, 7720–7733. doi:10.1021/acs.joc.2c00308.

[1] Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2023 ACD/Labs). Retrieved from SciFinder. [2023-11-30].

[2] 邢其锋; 丰佩川; 孙伟; 胡灵峰; 陈跃. 一种化合物、空穴传输材料、有机电致发光器件和显示装置. 2020. CN111732530A

[3] Xiaogang Yang, Dong Lu, Wenjian Guan, Shuang-Feng Yin, Nobuaki Kambe, and Renhua Qiu. Synthesis of (Deoxy)difluoromethylated Phosphines by Reaction of R2P(O)H with TMSCF3 and Their Application in Cu(I) Clusters in Sonogashira Coupling. J. Org. Chem. 2022, 87, 12, 7720–7733. doi:10.1021/acs.joc.2c00308.

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