1,3,5-金刚烷三醇

1,3,5-金刚烷三醇
识别
CAS号	99181-50-7
性质
化学式	C10H16O3
摩尔质量	184.23 g·mol−1
熔点	203—207 °C（476—480 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,3,5-金刚烷三醇是一种有机化合物，化学式为C₁₀H₁₆O₃。它可由金刚烷和三氧化铬在乙酸水溶液中的氧化反应制得；^[2]甲基(三氟甲基)过氧化酮也可作为氧化剂，反应除了1,3,5-三醇外还会得到1,3,5,7-四醇。^[3]它和溴乙酰溴反应，可以得到金刚烷-1,3,5-三基三(溴乙酸酯)。^[4]

参考文献

^ Rossella Mello, Luigi Cassidei, Michele Fiorentino, Caterina Fusco, Ruggero Curci. Oxidations by methyl(trifluoromethyl)dioxirane. 3. Selective polyoxyfunctionalization of adamantane. Tetrahedron Letters. 1990, 31 (21): 3067–3070 [2021-11-20]. doi:10.1016/S0040-4039(00)89027-9. （原始内容存档于2018-06-13）（英语）.
^ Shu-Qin Fu, Jian-Wei Guo, Dong-Yu Zhu, Zhe Yang, Chu-Fen Yang, Jia-Xing Xian, Xiong Li. Novel halogen-free flame retardants based on adamantane for polycarbonate. RSC Advances. 2015, 5 (82): 67054–67065 [2021-11-20]. ISSN 2046-2069. doi:10.1039/C5RA10887J （英语）.
^ Crandall, Jack K.; Curci, Ruggero; D'Accolti, Lucia; Fusco, Caterina. Methyl(trifluoromethyl)dioxirane. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2005. 1-6. ISBN 978-0-470-84289-8.
^ Hua Zhu, Jianwei Guo, Chufen Yang, Sa Liu, Yingde Cui, Xing Zhong. Synthesis of Adamantane-Based Trimeric Cationic Surfactants. Synthetic Communications. 2013-04-18, 43 (8): 1161–1167 [2021-11-20]. ISSN 0039-7911. doi:10.1080/00397911.2011.625134 （英语）.

[1] Rossella Mello, Luigi Cassidei, Michele Fiorentino, Caterina Fusco, Ruggero Curci. Oxidations by methyl(trifluoromethyl)dioxirane. 3. Selective polyoxyfunctionalization of adamantane. Tetrahedron Letters. 1990, 31 (21): 3067–3070 [2021-11-20]. doi:10.1016/S0040-4039(00)89027-9. （原始内容存档于2018-06-13）（英语）.

[2] Shu-Qin Fu, Jian-Wei Guo, Dong-Yu Zhu, Zhe Yang, Chu-Fen Yang, Jia-Xing Xian, Xiong Li. Novel halogen-free flame retardants based on adamantane for polycarbonate. RSC Advances. 2015, 5 (82): 67054–67065 [2021-11-20]. ISSN 2046-2069. doi:10.1039/C5RA10887J （英语）.

[3] Crandall, Jack K.; Curci, Ruggero; D'Accolti, Lucia; Fusco, Caterina. Methyl(trifluoromethyl)dioxirane. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2005. 1-6. ISBN 978-0-470-84289-8.

[4] Hua Zhu, Jianwei Guo, Chufen Yang, Sa Liu, Yingde Cui, Xing Zhong. Synthesis of Adamantane-Based Trimeric Cationic Surfactants. Synthetic Communications. 2013-04-18, 43 (8): 1161–1167 [2021-11-20]. ISSN 0039-7911. doi:10.1080/00397911.2011.625134 （英语）.

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