癸五炔
| 癸五炔 | |
|---|---|
| 识别 | |
| CAS号 | 32597-32-3 
|
| SMILES |
|
| 性质 | |
| 化学式 | C10H2 |
| 摩尔质量 | 122.12 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
癸五炔是一种有机化合物，化学式为C10H2。它可由碳化钙和含Cu+/Cu2+的氯化铵溶液反应制得，该反应还会生成己三炔和辛四炔等多炔副产物。[1]它可以通过与银氨溶液反应来提纯。[2]它在紫外线[3]或γ射线[4]下可以发生分解。它可以和碘形成分子配合物。[5]
参考文献
[编辑]- ^ (a) Franco Cataldo. The simplest approach to prepare solutions of polyynes in hydrocarbons. Tetrahedron Letters, 2005. 46 (21): 3665-3667. doi:10.1016/j.tetlet.2005.03.160; (b) Franco Cataldo. A method for synthesizing polyynes in solution. Carbon, 2005. 43 (13): 2792-2800. doi:10.1016/j.carbon.2005.05.024.
- ^ Liang Fang; et al. Purification of polyynes via carbides. Carbon, 2021. 179. 28-32. doi:10.1016/j.carbon.2021.04.032.
- ^ Cataldo, Franco; Strazzulla, Giovanni; Iglesias-Groth, Susana (2008). UV photolysis of polyynes at λ=254 nm and at λ>222 nm. International Journal of Astrobiology, 7(2). doi:10.1017/S147355040800414X
- ^ Cataldo, Franco; Ursini, Ornella; Angelini, Giancarlo; Strazzulla, Giovanni (2008). Polyynes Decomposition with γ Radiation. Fullerenes, Nanotubes and Carbon Nanostructures, 16(4), 272–281.doi:10.1080/15363830802171859
- ^ Wada, Yoriko; et al. Spectroscopic characterization of a series of polyyne-iodine molecular complexes H(C≡C)nH(I6) of n = 5-9. Chemical Physics Letters (2012), 541, 54-59. doi:10.1016/j.cplett.2012.05.035