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四(五甲基环戊二烯基镓)合铂

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四(五甲基环戊二烯基镓)合铂
识别
CAS号 561055-19-4  checkY
SMILES
 
  • CC=12C3(C)=C4(C)[C-]5(C)C1(C)[Ga+]2345[Pt]([Ga+]6789C=%10(C)C9(C)=C8(C)[C-]7(C)C%106C)([Ga+]%11%12%13%14C=%15(C)C%14(C)=C%13(C)[C-]%12(C)C%15%11C)[Ga+]%16%17%18%19C=%20(C)C%19(C)=C%18(C)[C-]%17(C)C%20%16C
性质
化学式 C40H60Ga4Pt
摩尔质量 1014.88 g·mol−1
外观 橙色晶体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

四(五甲基环戊二烯基镓)合铂是一种有机镓(I)化合物,化学式为C40H60Ga4Pt,或写作(Cp*Ga)4Pt(Cp*为五甲基环戊二烯阴离子)。它可由Pt(COD)2和GaCp*在己烷中反应制得。[1]

它可以和[Ga2Cp*][BArF](BArF为四[3,5-二(三氟甲基)苯基]硼酸根)反应,可以得到[GaPt(GaCp*)4][BArF]。[2]

参考文献

[编辑]
  1. ^ 1.0 1.1 Christian Gemel; Tobias Steinke; Dana Weiss; Mirza Cokoja; Manuela Winter; Roland A. Fischer. [M(GaCp*)4] (M = Pd, Pt) as Building Blocks for Dimeric Homoleptic Cluster Compounds of the Type [MPt(GaCp*)5]. Organometallics 2003, 22, 13, 2705–2710. doi:10.1021/om021003i
  2. ^ Buchin, Beatrice; Gemel, Christian; Cadenbach, Thomas; Fernandez, Israel; Frenking, Gernot; Fischer, Roland A. Organic group 13 complexes of d-block elements, XLIV. "Naked" Ga+ In+ as pure acceptor ligands: structure and bonding of [GaPt(GaCp*)4][BArF]. Angewandte Chemie, International Edition (2006), 45(31), 5207-5210. doi:10.1002/anie.200601007.